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为了弄清楚煤矸石回填地基对复垦区的环境效应,以开滦矿区吕家坨复垦新村为例,介绍了地基回填煤矸石工艺,分析了煤矸石化学成分及其含量;采用室内淋溶实验,对pH、总硬度(CaCO3)、F^-、SO4^2-、Pb、Cd和Cr^6+浓度等地下水环境质量指标进行分析,探讨了煤矸石回填地基对水环境的影响;讨论了煤矸石回填地基对大气质量的影响;参照《城市放射性废物管理办法》规定,评价了回填地基煤矸石的放射性对人体健康的危害。结果表明:通过现场振动压实试验确定了回填地基分层充填、分层振动压实参数及碾压趟数,确定按照煤矸石与土体积之比5:2进行回填,若回填一层厚500mm煤矸石,则要回填一层厚200mm粉煤灰或土,地表覆土厚度确定为0.5m;煤矸石中SiO2和Al2O3含量较高,属基性岩类,同时煤矸石含有炭、铝和CaO等物质,易发生水解和风化等现象;地基分层回填压实的复垦工艺减少了煤矸石中有害物质的释放量,降低了污染物的迁移速度,不会对水环境造成污染;地基回填煤矸石也显著减少粉尘和有害气体的排放量,降低对大气的污染;研究区煤矸石不属于放射性废物,不会影响人体健康,可作为建筑材料使用。 相似文献
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为了考察铁锰氧化物对酚类污染物的氧化降解能力,采用天然以及合成的铁锰氧化物对苯酚的氧化降解进行对比实验研究。土壤中铁锰氧化物样品分别为天然针铁矿及氧化锰,合成铁锰氧化物样品分别为合成针铁矿及软锰矿。结果表明:苯酚与铁锰氧化物发生氧化还原作用时,还可能与土壤中杂质发生吸附等作用;铁锰氧化物还原反应强度随着反应介质pH值的升高而迅速下降;可用零级反应动力学方程拟合铁氧化物还原溶解反应,针铁矿溶解反应的强度与介质的pH值呈负相关关系;天然针铁矿对酚类污染物的氧化降解能力明显高于合成针铁矿,pH值对天然针铁矿溶解反应影响较大;可用一级指数衰减方程拟合锰氧化物还原溶解反应,锰氧化物溶解反应的强度与介质的pH值呈指数衰减关系;pH值对软锰矿还原溶解反应的影响大于对土壤中氧化锰的影响,pH值越小,影响越显著;对比pH值对铁和锰还原作用的影响发现,在pH=6.5时,锰氧化物仍有较强的氧化性能。 相似文献
55.
Watershed water quality models are increasingly used in management. However, simulations by such complex models often involve significant uncertainty, especially those for non-conventional pollutants which are often poorly monitored. This study first proposed an integrated framework for watershed water quality modeling. Within this framework, Probabilistic Collocation Method (PCM) was then applied to a WARMF model of diazinon pollution to assess the modeling uncertainty. Based on PCM, a global sensitivity analysis method named PCM-VD (VD stands for variance decomposition) was also developed, which quantifies variance contribution of all uncertain parameters. The study results validated the applicability of PCM and PCM-VD to the WARMF model. The PCM-based approach is much more efficient, regarding computational time, than conventional Monte Carlo methods. It has also been demonstrated that analysis using the PCM-based approach could provide insights into data collection, model structure improvement and management practices. It was concluded that the PCM-based approach could play an important role in watershed water quality modeling, as an alternative to conventional Monte Carlo methods to account for parametric uncertainty and uncertainty propagation. 相似文献
56.
Orkun I. Davutluoglu Galip Seckin Cagatayhan B. Ersu Turan Yilmaz Bulent Sari 《洁净——土壤、空气、水》2011,39(2):185-194
The aim of this study was to assess the level of heavy metals (Al, Cd, Cr, Cu, Fe, Mn, Ni, Pb, and Zn) contamination and enrichment in the surface sediments of the Seyhan River, which is the receiving water body of both treated and untreated municipal and industrial effluents as well as agricultural drainage waters generated within Adana, Turkey. Sediment and water samples were taken from six previously determined stations covering the downstream of the Seyhan dam during both wet and dry seasons and the samples were then analyzed for the heavy metals of concern. When both dry and wet seasons were considered, metal concentrations varied significantly within a broad range with Al, 7210–33 967 mg kg?1 dw; Cr, 46–122 mg kg?1 dw; Cu, 6–57 mg kg?1 dw; Fe, 10 294–26 556 mg kg?1 dw; Mn, 144–638 mg kg?1 dw; Ni, 82–215 mg kg?1 dw; Pb, 11–75 mg kg?1 dw; Zn, 34–146 mg kg?1 dw in the sediments while Cd was at non‐detectable levels for all stations. For both seasons combined, the enrichment factor (EF) and the geo‐accumulation index (Igeo) for the sediments in terms of the specified metals ranged from 0.56 to 10.36 and ?2.92 to 1.56, respectively, throughout the lower Seyhan River. The sediment quality guidelines (SQG) of US‐EPA suggested the sediments of the Seyhan River demonstrated “unpolluted to moderate pollution” of Cu, Pb, and Zn, “moderate to very strong pollution” of Cr and Ni. The water quality data, on the other hand, indicated very low levels of these metals suggesting that the metal content in the surface sediments were most probably originating from fine sediments transported along the river route instead of water/wastewater discharges with high metal content. 相似文献
57.
Effects of Watershed Land Use and Lake Morphometry on the Trophic State of Chinese Lakes: Implications for Eutrophication Control 总被引:1,自引:0,他引:1
Water quality in lakes is influenced by a large number of watershed and lake characteristics. In this study, we examined the relative effects of watershed land use and lake morphology on the trophic state of 19 lakes in the Yunnan plateau and lower Yangtze floodplain, the two most eutrophic regions in China. Trophic state parameters consisted of total nitrogen, total phosphorus, chemical oxygen demand, chlorophyll‐a, Secchi depth, and trophic state index, while lake morphometric variables included area, maximum depth, mean depth, water residence time (WRT), volume, and length to width ratio. Percentages of forest, grassland, cropland, unused land, built‐up land, and water body in each lake's watershed were extracted from a land use map interpreted from Landsat TM images. A t‐test indicated that lower Yangtze floodplain lakes were shallower and had higher percentages of cropland and built‐up land in watersheds than Yunnan plateau lakes. Pearson's correlation analysis indicated that both watershed land use and lake morphometric variables were significantly related to most of the trophic state parameters. However, stepwise regression analyses demonstrated that the trophic state of the lower Yangtze floodplain lakes was mainly controlled by the percentages of cropland and built‐up land in watersheds, while that of Yunnan plateau lakes was mostly determined by the lake depth and WRT. These results suggest that the relative effects of watershed land use and lake morphology on lake trophic state are dependent on the lake's location. This study can provide some useful information in watershed land use management for controlling eutrophication in Chinese lakes. 相似文献
58.
矿产资源的持续开采与加工利用使得矿区周边水资源受到的污染日趋严重,急需采用先进技术对水污染进行监测分析,遥感技术是水环境监测最为有效的技术之一。利用国产环境一号小卫星多光谱遥感影像数据,针对福建省龙岩市紫金山矿区不同时相的数据进行水质遥感监测。利用近红外单波段阈值分割法提取悬浮物浓度信息,基于矿区酸碱性水体光谱曲线特性采用342波段假彩色合成影像,采用SVM分类方法进行分类,判别矿区水体酸碱性以及分析水体受污染程度变化和污染源。结果表明,研究区汀江水体2008年呈现碱性,2010年呈现弱碱性,水质在研究时段内得到一定的改善,但在选矿厂与矿区附近的水体中仍含有大量重金属沉积物。 相似文献
59.
为了更好地进行水体油污染监测,首先简要介绍了多角度偏振探测技术,然后着重分析了水体油污染目标的偏振特性,同时从目标地物反射光谱的偏振探测机理出发,讨论了它们偏振光谱的空间特征,并总结出3条普适规律.结果显示:偏振光谱信息与强度辐射光谱信息相比,目标地物间反射光谱的微小差异得到了增强,且在大角度入射时,增强效果更为明显.... 相似文献
60.
利用2006~2008年2月逐日地面常规观测资料和高空探测资料以及逐日的污染监测资料,统计分析了哈尔滨市2月风速、逆温和大气稳定度与大气污染的概率关系。分析结果表明:哈尔滨市2月的大气污染主要发生在风速〈3 m/s,污染物浓度随着风速的增大而减小,在一定程度上反映了哈尔滨市2月的污染主要是局地污染物的累积;发生大气污染时一定有逆温出现,但有逆温时不一定就发生大气污染;大气稳定度增加,大气污染概率增大。 相似文献